Brand Name: | Shanghai Sinofluoro Scientific Co., Ltd |
---|---|
Grade Standard: | Medicine Grade |
Type: | Auxiliaries and Other Medicinal Chemicals |
Place of Origin: | China (Mainland) |
MF: | C24BF20.C19H15 |
CAS No.: | 136040-19-2 |
Quick Details
Specifications
Alternate Name: triphenylcarbenium tetrakis(pentafluorophenyl) borate.
Physical Data: mp 180–182?°C.
Solubility: soluble in CH2Cl2, MeOH, and acetone, but its yellow color disappears because these solvents coordinate to the trityl salt.
Form Supplied in: yellow powder; commercially available from Asahi Glass Co. Ltd.
Analysis of Reagent Purity: NMR, mp.
Preparative Methods: trityl tetrakis(pentafluorophenyl)borate is prepared by mixing LiB(C6F5)4 and trityl chloride in hexane and refluxing overnight. It is prepared also by one-pot procedure starting from bromopentafluorobenzene.
Purification: recrystallization from CH2Cl2/hexane.
Handling, Storage, and Precautions: should be stored in a dry, dark, and cold place; stable at room temperature for long periods; does not decompose upon exposure to air.